Convert a saved game from Bleach: Heat The Soul 2 on your Memory Stick DUO.

Convert a saved game from Bleach: Heat The Soul 3 on your Memory Stick DUO.

Successfully complete all missions in Mission Battle mode to unlock Nell.

Successfully complete all twenty Story missions under the Mission Battle option to unlock the Karakura Heroes match.

Successfully complete the indicated task to unlock the corresponding playable character:

Byakuya Bankai: Successfully complete Story Mission 17.
Hisagi Shuuhei: Successfully complete Time Attack mode with Komamura Sajin.
Hitsugaya Bankai: Successfully complete Story Mission 9.
Ise Nanao: Successfully complete Time Attack mode with Kyouraku Shunsui.
Ishida Quincy Final Stage: Successfully complete Story Mission 6.
Komamura Sajin: Successfully complete Time Attack mode with Yamamoto Genryuusai Shigekuni.
Kurotsuchi Nemu: Successfully complete Time Attack mode with Kurotsuchi Mayuri.
Kusajishi Yachiru: Successfully complete Time Attack mode with Zaraki Kenpachi.
Kyouraku Shunsui: Successfully complete Time Attack mode with Ukitake Jyuushirou.
Renji Bankai: Successfully complete Story Mission 12.
Rukia Shinigami: Successfully complete Time Attack mode with Kuchiki Rukia.
Ulquiorra: Successfully complete the Karakura Heroes match.

Play Soul Road on the Normal or Hard difficulty setting with the indicated character. When a question is answered correctly, the answer will be the name of the character that is unlocked. You must hit the blue spot with at least 60% Trust so that the question appears.

Hanatarou: Play as Ichigo or Bankai Ichigo
Iba Tetsuzaemon: Play as Rangiku
Ikkaku: Play as Renji or Bankai Renji
Isane: Play as Hinamori
Isshin: Play as Chad
Karin: Play as Chad
Keigo: Play as Ichigo or Bankai Ichigo
Kojima Mizuiro: Play as Ichigo or Bankai Ichigo
Kon: Play as Rukia or Shinigami Rukia
Kuukaku: Play as Yoruichi
Tousen: Play as Gin
Unohana: Play as Ishida or Final State Quincy Ishida
Ururu: Play as Urahana
Yumichika: Play as Kenpachi
Yuzu: Play as Urahana